Accounting for Interelement Interferences in Atomic Emission Spectroscopy: A Nonlinear Theory
نویسندگان
چکیده
The article describes a nonlinear theory of how the presence third elements affects results analyzing elemental composition substances by means atomic emission spectroscopy. is based on assumption that there an arbitrary relationship between intensity analytical line analyte and concentration impurities alloying elements. has been tested simulation problem using commercially available equipment (the SPAS-05 spark spectrometer). By comparing proposed algorithm with traditional one, which assumes linear intensities spectral lines (or concentrations) in substance, it was revealed severalfold decrease deviations nominal impurity concentrations from measured ones. this study allow for reducing number procedures used materials have different compositions same matrix element. For instance, becomes possible to determine iron-based alloys (low-alloy carbon steels; high-speed high-alloy, heat-resistant steels) one calibration curve within framework universal method.
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ژورنال
عنوان ژورنال: Applied sciences
سال: 2021
ISSN: ['2076-3417']
DOI: https://doi.org/10.3390/app112311237